Furlani, Claudio and Zinato, Edoardo and Culot, Giorgio:
Complessi dell'iridio con [SnCl3]-
Atti della Accademia Nazionale dei Lincei. Classe di Scienze Fisiche, Matematiche e Naturali. Rendiconti Serie 8 41 (1966), fasc. n.1-2, p. 69-78, (Italian)
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Sunto
A detailed spectrophotometric investigation of the reaction between [IrCl6]3- or [IrCl6]2- and tin(II)chloride in hydrochloric solutions over a wide range of the concentrations of SnCl2 and HCl, shows occurrence of complex equilibria among at least three species of compounds containing iridium-tin bonds, whose existence ranges are delimited. Isolation and characterization of solid products containing the mononuclear anion [IrIIICl2(SnCl3)4]3- with iridium-tin bonds are described. The differences in behaviour between rhodium and iridium in the investigated reaction and the possibility of formation of mononuclear and binuclear Rh-Sn and Ir-Sn complexes are discussed.
Referenze Bibliografiche
[1]
C. FURLANI,
E. ZINATO e
F. FURLAN, «
Atti Acc. Naz. Lincei, Classe Sci. fis. mat. e nat.», serie VIII,
38, 517 (
1965). |
fulltext bdim |
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Con il contributo del Ministero per i Beni e le Attività Culturali